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Diana Rigg, On Her Majesty's Secret Service
Image credit: On Her Majesty's Secret Service: Everett Collection

3. Tracy di Vicenzo (Diana Rigg)

On Her Majesty's Secret Service (1969)

As it happened, Rigg replaced fellow Bond girl Honor Blackman on TV's The Avengers, where her Emma Peel became renowned as the toughest of dames. Opposite one-time 007 George Lazenby, however, she gave the series' most heartfelt and least comic performance as a lovelorn Mafia heiress, the only woman you could imagine the superspy settling down with.

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