3. MR. & MRS. SMITH (2005)
The power couple as action heroes: Brad Pitt and Angelina Jolie made a movie about John and Jane, married assassins who must take each other out with really big guns, which ends up turning them on — on screen and in real life, as it happened.
Sexiest Moment Angry, aroused, and armed to the teeth, they hit the dance floor to surreptitiously pat each other down. Quips hubby to his touchy-feely wife: ''That's all John, sweetheart.''
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